Introduction

Why the Periodic Table of Elements Is More Important Than Ever

Dmitri Mendeleev, inventor of the periodic table, circa 1880-82. Photographer: Andrei Osipovich Kareli/Alamy

The inventor Buckminster Fuller once described technological progress as “ephemeralization.” Sunbeams and breezes are replacing coal and oil as energy sources, brands are more important than buildings to corporations, and fiat money has supplanted gold and silver. So it seems reasonable to conclude that the periodic table of elements—that wonky taxonomy of physical stuff such as copper, iron, mercury, and sulfur—is passé, no more relevant than a manual typewriter.

Except exactly the opposite is true. Matter still matters. And on the 150th anniversary of the periodic table’s formulation by the Russian chemist Dmitri Mendeleev, it’s more important than it’s ever been. Read More

The Periodic Table at 150

Scientists have long sought to catalog the known elements: In 1789, Antoine Lavoisier sorted them by their properties. By 1808, John Dalton was listing them by atomic weight. In 1864, John Newlands argued for a law of octaves, asserting that every eighth element had similar attributes. But it took Dmitri Mendeleev to create a genuinely systematic and predictive table.

Born in Tobolsk, Siberia, in 1834, the youngest of more than a dozen children, Mendeleev graduated from the Main Pedagogical Institute in St. Petersburg in 1855. He studied chemistry in Heidelberg and Paris, then earned a doctorate back home and became a tenured professor at Saint Petersburg Imperial University. Dissatisfied by existing Russian inorganic chemistry textbooks, he decided to write one himself.

The work Mendeleev published beginning in 1869 both laid out the periodicity of the elements and predicted spaces for ones not yet identified. With the discovery of gallium in 1875, scandium in 1879, and germanium in 1886, the theories underlying the table were shown to be true. Increasing scientific acceptance of these theories accelerated research into the material world and its industrial and commercial applications. Mendeleev himself took part in this, investigating processes related to Russian coal, oil, and even cheese production during the country’s fitful drive to modernize.

Since his death from influenza in 1907, the table has changed some, but its fundamental organization remains. Each element has a one- or two-letter chemical symbol, usually derived from its common name but sometimes from another language, making gold, for example, “Au” for the Latin aurum. The atomic number tallies the protons in the atom’s nucleus. The standard atomic mass is sometimes given to multiple decimal places, with the number in parentheses if it’s for the longest-lived isotope.

The columns depict elements that have similar chemical properties. The alkali metals, shown in the first column on the left, for example, have one electron in their outer shell and therefore tend to bond particularly well with the halogens, in the second column from the right, which have seven electrons in their outer shell and lack the single electron needed to complete it. That’s how we get compounds such as sodium chloride—table salt—and potassium iodide, which helps protect the thyroid from the effects of radiation.

The column on the far right shows the noble gases, whose outer electron shells are full, making most of these elements useful in lighting since they won’t react with others. In most periodic tables, the lanthanides and actinides are placed in rows at the bottom to avoid making the table impractically wide.

Mendeleev didn’t get everything right: He believed that elements were unique and resisted the idea that they had the same building blocks. He also produced a convoluted case that ether was an element. But he got the basic design right, and that’s why he’s regarded as its inventor today—and why its sesquicentennial is being celebrated as the International Year of the Periodic Table. —Joanna Ossinger

Hydrogen $0.01/liter, 99.95% Grade B gaseous

Getting on the Hydrogen Bus

In Europe’s electric vehicle capital, hydrogen fuel might finally have a future.
The Raggovidda wind farm on the Barents Sea coast. Video: Rocco Rorandelli for Bloomberg Businessweek
The building for the electrolyzer being constructed close to the port of the town of Berlevag. Photographer: Rocco Rorandelli for Bloomberg Businessweek
It may not look like it, but the building under construction to the left, near the Norwegian port of Berlevag, is about to become part of the world’s most efficient wind farm. By early next year, it will house a device called an electrolyzer, which, powered by that Norse wind, will produce hydrogen fuel for a growing army of forklifts, cars, trucks, and buses. A hydrogen station in the Oslo suburb of Hovik will soon be ready to fill them up.
Hydrogen tanks inside the Scania regional service center of Trondheim. Photographer: Rocco Rorandelli for Bloomberg Businessweek

The hydrogen-battery revolution has been 10 years away for decades now. But Norway, Europe’s No. 1 in electric vehicles, is on track to become a leading adopter of the universe’s most abundant element. Proponents say it will become an essential component of a more environmentally friendly future as a growing supply of renewably generated hydrogen makes the fuel more competitive.

One longtime knock on hydrogen fuel has been that fossil fuels are often required to generate it. Not so at the Berlevag wind farm, or in the Norwegian city of Trondheim, where a technician employed by Swedish vehicle manufacturer Scania AB is working with hydrogen electrolyzers and tanks that will be fueled by solar panels. This hydrogen setup will power a fleet of trucks and forklifts being tested for ASKO, a local grocery wholesaler.

For now, though, the dirtier forms of hydrogen production remain less than half as expensive as renewable ones. That’s a headache for Norway’s government, which plans to halt sales of fossil-fuel-powered cars by 2025 and expects to have as many as 500,000 hydrogen cars on the road in the country a few years later. At the very least, that would mean a lot more electrolyzers in places like Berlevag.

Helium $0.95/liter, 200-liter cylinder

We’re Running Out of Helium, and Two Geologists Might Have a Fix

MRI machines, fiber-optic cables, and kids’ birthday parties need it. Helium One wants to help. Read Story
Karim Mtili, a geology grad student, collects gas samples in Itumbula, Tanzania. Video: Adriane Ohanesian for Bloomberg Businessweek
Lithium $10.34/kg, 56.5% lithium hydroxide, China market

Storage Wars

If the 20th century was the age of the internal combustion engine, the 21st belongs to the battery. Within a few decades, batteries will probably be the dominant source of power propelling cars and trucks, and they could even become commonplace in helicopters and planes. Far from their golf cart predecessors, today’s electric vehicles can reach ludicrous speeds while emitting far fewer pollutants than gas guzzlers. They’re also easier to make, and their batteries can be recycled. Carmakers from General Motors Co. to BMW AG are spending billions of dollars to make environmentally friendly transportation a reality. But the effort comes with its own environmental hazards, and pressure is building to ensure the companies are sourcing the critical elements responsibly. It would be all too easy to fall into many of the same traps as the oil industry that EVs are meant to leave behind. In this issue we’ve taken a look at the raw materials in batteries, from lithium to cobalt to zinc, to see how their green credentials compare.

Lithium: The Water Guzzler


Abundance○○○○○
Mining practices○○○○○
Recycling & reuse○○○○○

  • Used in: Lithium-ion batteries powering cars, cellphones, and power tools
  • What it does: Enables energy to pass between the batteries’ positive and negative electrodes
  • Achilles’ heel: If prices stay low, mining, exploration, and recycling might not be worth the cost. That would leave the industry more reliant on an environmentally riskier method known as brine extraction, which involves pumping underground saltwater reserves and extracting the lithium through evaporation.
Beryllium $500/kg, U.S. market

A Very High-End Bike

A BE401 mountain bike manufactured by Beyond Bicycles and made with beryllium. Courtesy Chris Hinshaw

Tougher than steel, lighter than aluminum, rather rare, and toxic if inhaled, beryllium is normally reserved for use in such high-tech applications as X-ray machines, spaceships, and nuclear reactors and weapons.

But in the 1990s former triathlete Chris Hinshaw spotted a market opportunity: bicycles. His company in San Jose, Beyond Beryllium Fabrications, made about 100 bikes with the metal. Most were built using aluminum-beryllium alloys and sold for about $1,900; ones with weapons-grade beryllium went for as much as $30,000. Customers included baseball star Chili Davis.

Hinshaw stopped making beryllium bikes after a few years because his main supplier, a Russian mine and refinery, became unreliable. “When the Soviet Union fell, we realized right away that there wasn’t an infrastructure in place, not only to make product but do it to the standards and expectations set forth in the bicycling industry,” he says.

Boron $0.43/kg, average value of U.S. imports

Total Borons?

In our Oct. 20, 1956, issue, BusinessWeek predicted “a host of big exciting new uses” for boron, particularly in jet fuel. A few years later, scientists realized that boron-based fuels are highly toxic—and also prone to spontaneously combust. Luckily for us, boron continued to prove useful in a growing array of other products, including laundry detergent, fertilizer, and LCD screens. We wound up being right, just not for the reasons we thought.

Carbon $0.11/kg, minimum carbon price recommended by the UN Global Compact

The Everything Atom

If chemistry were fair, the 118 elements would distribute themselves evenly among the 154 million substances in the American Chemical Society’s CAS Registry. It’s not. All but about 2 million have a molecular scaffolding of atom No. 6, carbon. It’s the diamond on the ring, and also a good bit of the finger wearing it. Here, by size and date of discovery, are a few mighty molecules brought to you by the letter C.
Nitrogen $0.10/kg, 99.99% Grade B liquid
Oxygen $0.17/kg, 99.6% Grade A liquid

Nitro Pour

Nitro cold brew. Photo: iStock/Getty Images

There’s not much that can change how you make a cup of coffee, pumpkin spice notwithstanding. Beans are roasted, ground, and then steeped in water with or without pressure. But in recent years, there’s been a major update to your basic cup of joe: pumping odorless nitrogen gas into brewed coffee to add frothiness and the tiniest hint of sweetness. A good nitro cold brew will look like an inviting beer, with a soft, foamy top. Since the first one flowed from an Austin tap around 2012, according to the most popular origin story, it’s become a staple for coffeeheads and a driver in the $4.1 billion ready-to-drink coffee category.

Stumptown Coffee Roasters Inc., the Portland, Ore.-based national chain, first offered cans of nitro brew in 2015 after experimenting with draft versions. With sales of about 2 million cans a year, it’s the company’s fastest-growing product. Early on, says head brewer Brent Wolczynski, “the process was very DIY. We would put cold brew in a keg, hit it with nitrogen at a really high pressure, and just shake it around.”

Now the process is the equivalent of a marvelous science experiment: Each can is equipped with a small plastic widget that encloses the nitrogen. Cracking open the can exposes the brew to atmospheric pressure, pushing the nitrogen out and through the coffee. The result is a cascade of tiny bubbles as you pour.

La Colombe Coffee Roasters, another premier brand, includes nitrogen’s periodic table mate, oxygen, in its version. The draft latte is made with nitrous oxide (N2O), a compound more famously known as laughing gas, that’s also used to animate canned whipped cream. A customized valve delivers the kind of foam typically found in a hot latte into the cold beverage. N2O bubbles last longer than nitro’s and create an extra-creamy texture with a more pronounced sweetness. La Colombe has even patented its can.

Another big name in coffee, Starbucks Corp., has announced that its nitro cold brew will be sold on tap nationwide by yearend. No surprise, it will be available in several flavors and finishes, like one with a “cascara cold foam” and another with “sweet cream.” There’ll even be a pumpkin cream cold brew.

Composition

Night Vision Binoculars

Night vision technology has become reliable and widespread, used by everyone from soldiers to birders. Although a digital approach is becoming popular, light intensification remains the industry standard. As moonlight reflected off an object enters these battery-powered binoculars, it passes through the lens into an image-intensifying tube. A photocathode then converts the light into electrons that are amplified by a photomultiplier and directed toward a phosphorescent screen to produce a visible image. —E. Tammy Kim

Photographer: Daniel Shea for Bloomberg Businessweek. Prop stylist: Anna Surbatovich. Product courtesy Night Owl Optics, First Texas Products LLC
Fluorine $1,528/kg, Swix high-fluoro wax

Cross-Country Skiing’s Dirty Little Fluorinated Secret

Professionals and amateurs alike are hooked on fluoro wax, but the EU is banning it. Read Story
A bar of Swix high fluoro ski wax. Photographer: Evan Ortiz for Bloomberg Businessweek
Neon $2/liter, 200-liter cylinder

Lights Lights Lights

Scientists discovered the presence of neon in the atmosphere at the end of the 19th century. The element and its fellow noble gases—including argon, krypton, and radon—are tasteless, odorless, colorless, and largely unreactive. But when subjected to an electrical charge, they emit various colors. In the 1920s entrepreneurs recognized the advertising potential of this, and within a few years neon signs had started changing the face of the world’s cities. They eventually defined the appearance of iconic locations, such as New York City’s Times Square and the Las Vegas Strip.
Neon creates the red-and-orange glow most commonly associated with the lights, whose colors depend on the gas, or combination of gases, in the tubes. By the 1970s, Hong Kong had emerged as one of the world’s great neon cities. Signs jostled for placement in its narrow streets as restaurants, clubs, and movie theaters tried to outdo each other in style and size. Read more at argon, krypton, and xenon. Video: Tommy Trenchard for Bloomberg Businessweek
Sodium $110/kg, 5-pound bag of Jacobsen pure flake finishing salt

The Salt King of America

Ben Jacobsen wants people to think differently about the power of salt. Read Story
Ben Jacobsen, founder of Jacobsen Salt Co. Photographer: Shawn Records for Bloomberg Businessweek
Magnesium $4.74/kg, U.S. spot

Flashback

Two children in a tenement room, circa 1910. Photographer: Jessie Tarbox Beals; Courtesy Community Service Society of New York/Rare Book and Manuscript Library/Columbia University

Light is and always has been the photographer’s greatest concern. But in the mid-19th century, the task of capturing and creating light was all-consuming. In 1864, Alfred Brothers, the son of an English chemist, began to experiment with a primitive flash—essentially, a metal-burning lamp.

The key was magnesium, a remarkably lightweight silvery metal. At No. 12 on the periodic table, toward the top left corner, it’s one of the most common elements on Earth, yet it’s never found in its pure form. On its own, magnesium burns slow and clear and gives off a bright, neutral light—no blue or yellow sheen.

Brothers took a chunk of magnesium ore, bathed it in acid, mixed it with salt, burned it, and captured the vaporized condensation. He hammered this purified metal lump into a sheet, then cut it into ribbons that could be lit like candle wicks. He placed this controlled fire next to his enormous, boxy camera and made a portrait in his studio. “Henceforth it will be next to impossible for mortal man to hide himself from the lens of the photographer. Formerly we were safe after sunset, but that is no longer,” a London journalist wrote in the Standard. Soon, adventurers such as Charles Piazzi Smyth were taking magnesium on the road to shoot the first scenes of caverns and the insides of the Great Pyramid of Giza.

Piazzi Smyth: Inside the Great Pyramids. Courtesy SSPL/Getty Images
Family around a piano, New York City, circa 1916. Photographer: Jessie Tarbox Beals; Courtesy Community Service Society of New York/Rare Book and Manuscript Library/Columbia University

By the 1880s, the magnesium flash had leapt from the toolbox of explorers to that of journalists. As the story goes, Jacob Riis, then a photographer for New York’s Evening Sun, read an article about a German manufacturer of flash powder and reacted “with an outcry that startled my wife. … A way had been discovered, it ran, to take pictures by flashlight.” Riis acquired a flash gun—which ignites magnesium powder inside a pistol—and took it with him to shoot the dark tenements of New York’s Lower East Side. Without magnesium, there would be no How the Other Half Lives.

There would also be no tenement pictures from Jessie Tarbox Beals, a schoolteacher-turned-photographer who shot portraits of early 20th century New Yorkers. She was, as historian Kate Flint writes in Flash!, a master of “the surprising illumination of the everyday.” In one especially notable Beals portrait, an unnamed woman sits on a kitchen chair, holding a naked infant in each arm, wearing a flat, tired expression. She and her babies are squeezed among mismatched cribs, a worn apple basket, an iron stove, pots, a kettle, and bottles and plates stacked in open cabinets. A calendar and a rag hang from the wall; the floor is all grimy tile. Has any room ever seen more life?

In the decades after Beals’s death in 1942, the magnesium flash evolved only in form. It went from the flash gun to the flashbulb—what we now imagine as a blinding burst in mid-20th century paparazzi shots. Dan Tidwell started out as a photographer in the final days of the magnesium flash. In 1965, at the age of 20, he was hired to document an historic project near Sacramento: the final testing stage of NASA’s Apollo program. Tidwell’s camera of choice was a large-format Graflex 4x5 with a large flashbulb attached to its right side. “It would not be uncommon for that glass bulb to literally explode,” he told me.

In one of his pictures, four men in white coveralls and hard hats stand in front of an enormous rocket. At right, a conical mass of wires, pipes, and balloons twists in shades of black and gray. At left, the flash has merged the men’s coveralls, the rocket’s curved body, and the wall of the hangar into a bleached plane.

Apollo tests. Photographer: Dan Tidwell

That flash-shocked aesthetic isn’t so popular these days. (Just one company, Meggaflash, in Ireland, still sells old-fashioned flashbulbs.) In July I attended a wedding in a dusky, jasmine-scented garden in Los Angeles. As soon as the ceremony began, nearly every guest raised her smartphone. Long after nightfall we continued to shoot without a flash, reflecting a shared preference for subtle edges. Only the wedding photographer used the occasional flash to interrupt our inky surroundings. He clicked the device onto the body of his camera and pressed the shutter. There was no acrid explosion or metallic smoke—just the memory of magnesium’s blinding light.

Aluminum $2.54/kg, ingot, U.S. market

Ink Think

The metallic color shown on this issue’s cover is Pantone 877 C, whose shimmery quality derives from aluminum flakes mixed into the ink.

Photographs for Bloomberg Businessweek by Tommy Trenchard (Neon), Shawn Records (Sodium), Kiliii Yuyan (Neodymium), Carlotta Cardana (Gold), and Christie Hemm Klok (Berkelium)
Silicon $3.04/kg, silicon metal, U.S. market

Sand Blasters

(From left) Sandcastle sand and frac sand. Photo: Getty Images

In hydraulic fracturing, or fracking, drillers pump a viscous, gritty goo down a well at pressures that splinter the rock beneath, releasing trapped oil and ­natural gas deposits. The resulting channels are kept open using grains of “proppant” suspended in the frac fluid. The most common proppant is sand.

Fracking is now the largest consumer of American sand. And not just any sand will do: The best has round, uniform grains and a high silica content that makes it hard enough to withstand being clamped between giant rocks. “The boom in U.S. hydrocarbon production depends on mining millions of tons of sand,” reads a pamphlet from proppant provider Hi-Crush Inc., “and pumping it back into the earth.”

Source

The most desirable frac sand comes from the Upper Midwest. Northern White and Ottawa White are particularly prized for their lack of impurities. Freight trains and barges transport the sand south to the Permian Basin and east to the Marcellus Shale. As the industry has grown, drillers trying to reduce transport costs have begun to look closer to fracking sites, excavating lower-quality Oklahoma sand and mining the dunes of West Texas.

Mining

Backhoes and loaders scoop sand up from shallow pits. The grains are washed, sorted for size through filters and centrifuges, then dried in rotating drums. Sometimes the sand is coated with resin to make it stronger.

Blending

Drillers store the sand on-site in silos or other containers. When needed, it’s mixed with water, chemicals, and thickeners such as guar gum in giant truck-mounted blenders before being pumped down the well.

Phosphorus $0.07/kg, phosphate rock, f.o.b. (free on board; prices include shipping and loading)

Conscious Fertilizer

Goats at Stone Barns. Courtesy Molly M. Peterson/Stone Barns Center for Food & Agriculture

Chemical fertilizer has helped feed the world since it was developed in 1909. But its damage to the Earth has been documented with increasing alarm. The farmers at Stone Barns Center for Food & Agriculture in Tarrytown, N.Y., are leading the way in eco-minded fertilization. On the 400-plus-acre property, donated by the Rockefeller family, cows, sheep, goats, pigs, and hens are rotated around different pastures, as is their manure, a major source of fertilizer. Phosphorus, a key element in the animal droppings, is one of the most carefully monitored on the property, says Stone Barns farm director Jack Algiere. He calls it the steroids of the plant world—combined with nitrogen and potassium, it can turn a humble zucchini into a show-stopping specimen.

Dan Barber, a chef and co-owner of the property’s Blue Hill at Stone Barns restaurant, wants to demonstrate that farmers can still profit if they give up what he calls “their single-nutrient obsession” with elements such as phosphorus and nitrogen. Just like too much of anything, excess phosphorus is harmful. Runoff containing the fertilizer blights waterways by stimulating overproduction of algae and weeds.

Westchester County, home of Stone Barns, has banned commercial phosphate fertilizer because of the threat it represents to the ecology of the Hudson River. Naturally derived phosphorus is less soluble—and not banned—so Stone Barns is in the clear.

Sulfur $0.08/kg, elemental sulfur, f.o.b.

Sulfur Is the Oil Industry’s Other Problem

The noxious byproduct has been linked to acid rain and lung cancer. Read Story
Sulfur crystals. Photographer: Susan E. Degginger/Science Source
Chlorine $0.33/kg, liquid contract, U.S. market

Political Chicken

Illustration: Steve Bell

There was a time—2017—when Brexit seemed to hang on chickens washed in chlorine. The sterilization practice is banned in Europe but common in the U.S., which insisted it wouldn’t sign a trade deal with a post-EU Britain that didn’t include its poultry. Two years, one prime minister, and no Brexit later, the possible arrival of chlorinated birds still rankles “remainers.”

Argon $0.48/liter, 200-liter cylinder

More Hong Kong Lights

The city’s signs have been disappearing by the day. The Hong Kong government has cracked down on signage it says doesn’t comply with building and safety codes. Many business owners replace the removed neon signs with cheaper mass-produced LED lights. Other shopkeepers have chosen to take down their signs because they look dated. “In the ’80s, if you walked down the streets, you’d see neon everywhere,” says Cardin Chan, executive director of the Hong Kong Neon Heritage group. The once-modern aesthetic is now more associated with seedy bars and red-light districts. Streets that once were bathed in neon often carry just a solitary, flickering sign—or none at all.
Argon is the third-most abundant gas in the atmosphere and the second-most common of the noble gases used in neon lights. It emits a pale blue-violet hue—the intensity of the color is weaker than the red of neon. A sign for the Hong Kong Cafe hangs over Tung Choi Street in the Mong Kok neighborhood. Photographer: Tommy Trenchard for Bloomberg Businessweek
A neon sign hangs above the Regency Spa in Yau Ma Tei. Photographer: Tommy Trenchard for Bloomberg Businessweek
Neon lights jostle among LED ones on Portland Street in Kowloon. Photographer: Tommy Trenchard for Bloomberg Businessweek
A neon sign advertises the Mido Cafe in Yau Ma Tei. Photographer: Tommy Trenchard for Bloomberg Businessweek
A half-illuminated neon sign hangs above a street market on Canton Road in Mong Kok. Streets that once were bathed in neon often carry just a solitary, flickering sign—or none at all. Photographer: Tommy Trenchard for Bloomberg Businessweek
Potassium $0.82/kg, potash, f.o.b.

Potash Mine

Using drones and advanced cameras, the Canadian artist Edward Burtynsky has captured the grisly beauty of global industry, from clear-cutting and strip mining to the mass slaughter of elephants. This 2017 photo comes from the Uralkali mine in Berezniki, Russia, where the potash salts containing potassium—a key component of commercial fertilizer—are extracted. On Sept. 25, Burtynsky will release his third documentary, Anthropocene: The Human Epoch, which chronicles humanity’s large-scale and now intractable alteration of the planet. —James Tarmy
Uralkali potash mine in Berezniki, Russia. Photographer: Edward Burtynsky; Courtesy Howard Greenberg and Bryce Wolkowitz Galleries, New York/Nicholas Metivier Gallery, Toronto
Calcium $6.27/kg, China spot

What If You Eat It?

Calcium is a soft, gray alkaline earth metal. It’s the fifth-most abundant element in the Earth’s crust. Photographer: Charles D. Winter/Science Source
  • Who eats calcium?
    Pretty much everyone. Since it’s most prevalent in dairy, vegans have to rely on leafy greens and supplements.
     
  • What does it taste like?
    Raw metallic calcium is unstable and highly reactive and would corrode the inside of your mouth. Most of us consume it in one of its chalky salt forms—calcium hydrogen phosphate (as in milk) or calcium carbonate (supplements).
     
  • What does it do?
    Calcium strengthens bones and teeth. If you don’t get enough, you can lose bone mass, leading to osteoporosis. If you get too much, you can become constipated. It may increase the risk of kidney stones as well. —Silvia Killingsworth
Scandium $5,592/kg, 99.95% total rare-earth mineral, China market

Coal Comfort

Duke Energy coal ash ponds in North Carolina. Photographer: Will Warasila

U.S. efforts to diversify its supply of rare-earth elements (REEs) have led to an unlikely source: coal. A program begun in 2014 aims to wean the U.S. from its dependence on China for these 17 difficult-to-extract minerals, essential to many high-tech applications including weaponry. “Our current projections are that if high REE extraction efficiencies are achieved, there are sufficient domestic coal-based resources available to supply the U.S. demand,” says Mary Anne Alvin, REE technology manager at the Department of Energy. Managers say the program’s 22 projects piggyback on existing coal mining and consumption and don’t cause additional environmental harm. The major challenge is to develop separation and concentration technologies that can be scaled up to viable commercial operations. Efficiently recovering scandium, a particularly expensive REE, would help achieve that goal. Here are two projects at different ends of coal’s production cycle.

North Dakota Coal Stocks

This project seeks to capture REEs from lignite, a low-grade coal. Nolan Theaker, technical lead of the University of North Dakota project, says extraction can be easier from lignite than from higher-rank coals. The prototype process crushes, screens, and chemically treats 44 pounds of lignite an hour to produce a third of an ounce of rare-earth oxide products—about 1/100th the amount needed for an electric vehicle motor, according to Theaker. He says the project will advance to half a ton of coal processed per hour for a planned pilot in 2023.

Kentucky Coal Ash

The advantage to extracting at the tail end of the process, according to Prakash Joshi, former head of the effort at Andover, Mass.-based Physical Sciences Inc., is that coal ash contains six to 10 times the concentration of REEs as unburned coal. The project’s pilot plant, to be completed in 2020, will wash the glassy matrix containing REEs out of half a ton of ash a day from a power plant in Ford, Ky., then use a chemical process to produce up to 17 ounces of dry material that’s at least 20% scandium and yttrium.

Composition

Computer Chip

Silicon Valley gets its name, of course, from element 14, the essential stuff of the computer chip. In the early days of computing, the three parts of a chip—the wafer, or substrate; the transistors layered on top; and the wires connecting to a circuit board—required only a handful of elements. Today, chipmakers draw on a large swath of the periodic table. —E. Tammy Kim

Photographer: Daniel Shea for Bloomberg Businessweek. Prop stylist: Anna Surbatovich. Product courtesy advanced science research center at the graduate center, CUNY.
Titanium $9.10/kg, titanium sponge metal

Card Creep

Courtesy Apple

“Stronger than steel at high temperatures, titanium got named after the Titans of Greek mythology,” says Bill Nye, aka the Science Guy. “Not only can it take the heat, it can reflect it.” That’s the kind of metal people want to associate themselves with—and the reason why, as the August release of the Apple card showed, titanium is the “it” material for credit cards. Even so, Apple Inc.’s laser-etched version joins a crowded metal-card bandwagon. Review website Credit Card Insider counts 22 on the market, which the companies tout as being made with titanium, or stainless steel (i.e., iron, carbon, and chromium), or even 24K gold.

For all the fervor, few are truly pushing the limits of metallurgy. JPMorgan Chase & Co. gets an honorable mention for its J.P. Morgan Reserve card—née the Palladium card and actually made with the platinum-group metals. Other companies might consider the:

  • VANADIUM CARD
    A proton above titanium
     
  • TIN CARD
    So far ahead of the pack you’re in back
     
  • PROMETHIUM CARD
    Only the rarest earth will do
     
  • TUNGSTEN CARD
    The true wolfram of Wall Street
     
  • MERCURY CARD
    The ultimate liquid asset
     
  • PLUTONIUM CARD
    Simply the bomb
Vanadium $30.86/kg, vanadium pentoxide

Ford’s Miracle Metal

Ford Model T, 1908. Courtesy Library of Congress

At the turn of a new century, Henry Ford, a two-time automobile-industry failure seeking a third crack, had an idea for a new kind of car. Early models coped with the rugged road conditions of the time through sheer heft, and they were expensive to make and buy. “The greatest need to-day,” Ford wrote in 1906, “is a light, low-priced car.”

Ford’s account of his eureka moment ran like this: The year before, at a race in Palm Beach, Fla., he’d seen a French driver crash. The vehicle was badly damaged, but its lightweight steel didn’t break. Ford salvaged a part from the wreck to investigate further; the steel, he learned, was a vanadium alloy. Historians are skeptical of the tale—there’s no record of a race in Palm Beach that year, let alone a crash, raising the less romantic possibility that Ford’s engineers read about vanadium steel in trade magazines. However it happened, the discovery was transformative. Ford placed an order for $750,000 (more than $17 million in today’s dollars) worth of vanadium steel with United Steel and the fledgling American Vanadium Co.

In October 1908 the first Model T rolled off the line. It was by far the lightest and cheapest car yet, with half its steel parts made using the vanadium alloy and a retail price of $850. An early print ad, showing dozens of children piled on top of one, proclaimed, “Only springs and axles of Vanadium Steel could safely carry such a load as this.” We all know what ensued: Fifteen million Model Ts sold in two decades. Mass production. The dawn of drive-ins and drive-thrus, the rise of the road trip. The interstate. Dean Moriarty. Thelma and Louise. And smog, gridlock, and greenhouse gases.

All of it came courtesy of a little-known metal that had been discovered only after a false start. In 1801 a Spanish mineralogist, Andrés Manuel del Río, claimed to have found a new element in a sample of a mineral he called “brown lead,” but his peers convinced him it was just a form of chromium. It was left to a Swedish chemist, Nils Gabriel Sefstrom, to rediscover the element 30 years later and name it after the Norse goddess Vanadis. Known for its stability at high temperatures and across valences, it was initially used to help set black dyes in fabrics and inks. By the turn of the century, it was being used in alloys for tools and dies.

After Ford came along, it became everyone’s not-so-secret ingredient. Mixing as little as 0.05% vanadium into a steel alloy can as much as double its strength—thanks, scientists now know, to the fine precipitation of vanadium carbonitrides as the steel cools. This reduces the amount of steel required for a given purpose, making it appealing for railways, rebar, and more.

And it’s still essential for automobiles. “The intensity of use of vanadium in cars is only increasing,” says Terry Perles, president of supplier Motiv Metals LLC. “It’s all about government-driven fuel economy standards.” A century ago, a lighter car meant an affordable car. Today it also means a more fuel-efficient one. Perles is excited, too, about the potential for vanadium-based batteries, which promise to reduce carbon emissions by storing vast solar power reserves. There are significant kinks to work out, but the next act for Henry Ford’s wonder metal could be undoing the excesses it helped engender.

Chromium $0.31/kg, chromium ore
Manganese $0.01/kg, 46%-48% metallurgical ore, China spot
Iron $0.08/kg, iron ore

Kabul’s Iron Lady

Nargis Nehan is trying to reform a troubled ministry and get her country’s vast mineral resources out of the ground. Read Story
Nargis Nehan, Afghanistan’s minister of mines and petroleum. Photograph by Kiana Hayeri for Bloomberg Businessweek
Cobalt $32.12/kg, London Metal Exchange cash spot
Nickel $15.88/kg, London Metal Exchange cash spot
Copper $5.68/kg, London Metal Exchange cash spot
Zinc $2.22/kg, London Metal Exchange cash spot

Storage Wars Continued

Assessing the raw materials in batteries to see how their green credentials compare.
*Based on December 2018 prices. Data: Bloomberg New Energy Finance

Cobalt: The Moral Problem


Abundance○○○○○
Mining practices○○○○
Recycling & reuse○○○○○

  • Used in: Lithium-ion batteries as part of the battery cathode.
  • What it does: Helps the battery maintain its structure and keeps it cool during charging and discharging.
  • Achilles’ heel: Congo, the world’s top producer, brings with its cobalt a raft of social and environmental concerns given the terrible, toxic conditions for mine workers, including children as young as 4. Related fatalities are rising; the industry has few answers.

Nickel: The Substitute


Abundance○○○○○
Mining practices○○○○○
Recycling & reuse○○○○○

  • Used in: Lithium-ion battery cathodes.
  • What it does: Boosts energy density to help electric vehicles travel faster and farther while also allowing battery makers to reduce their dependence on cobalt.
  • Achilles’ heel: Unproven production processes. If miners in Indonesia are unable to bring a steady supply of cheap, battery-grade nickel into production, the market will likely face a severe shortage, which could lead to a dearth of high-nickel batteries broadly believed to be the future of EVs.

Copper: The Safe Bet


Abundance○○○○○
Mining practices○○○○○
Recycling & reuse○○○○○

  • Used in: Electrical wiring in electric vehicle engines, charging stations, and cables.
  • What it does: Copper is the most conductive metal after silver and about one-hundredth of the price.
  • Achilles’ heel: People who insist climate change isn’t real. If the EV revolution proceeds apace, copper will be needed for whichever types of batteries win out. Electric vehicles require about 80% more copper than fossil fuel-burning cars.

Zinc: The Wild Card


Abundance○○○○○
Mining practices○○○○○
Recycling & reuse○○○○○

  • Used in: Zinc-air batteries for renewable energy installations and maybe EVs.
  • What it does: It’s used in the battery anode and reacts with air during the discharging process, yielding power.
  • Achilles’ heel: Investment. Billions of dollars continue to pour into the development of lithium-ion batteries, and advances in the incumbent technology are still coming hard and fast. If zinc-air batteries are going to take market share, they’ll need to prove themselves with far less money behind them.
Gallium $350/kg, high-quality refined
Germanium $1,300/kg, germanium metal
Arsenic $1.40/kg, arsenic metal, China market

An Obsession With a Useless Element Helped Build the Digital World

Gordon Teal’s dedication to germanium led to the first commercial transistors. Read Story
Gordon Teal (right), working on a junction transistor, 1950. Courtesy Nokia Bell Labs
Composition

Fiber Optics

A successor to the humble copper-wire telephone line, fiber optics carry all manner of data around the world in the form of light. Specialized fiber optics are also used in lasers, medical imaging, and underground sensors that detect faint vibrations or monitor temperature and pressure. —E. Tammy Kim

Photographer: Daniel Shea for Bloomberg Businessweek. Product courtesy OFS Fitel, Furukawa Electric Co.
Selenium $44.09/kg, U.S. market

What If You Eat It?

Brazil nuts. Photo: Zoonar GmbH/Alamy
  • Who eats selenium?
    You, if you take a multivitamin.
     

  • What does it taste like?
    It might taste like Brazil nuts, which have the highest concentration of selenium, followed by seafoods and organ meats.
     

  • What does it do?
    The mineral is an essential antioxidant. But too much of it can cause selenosis, a condition marked by hair loss, brittle nails, and a metallic taste in the mouth. —Silvia Killingsworth

Bromine $4.40-$5.40/kg, U.S. market

The Woman Who Got Bromine Out of Kids’ Pajamas Fears It’s Coming Back

Chemist Arlene Blum battles a new form of an old foe. Read Story
Arlene Blum hikes a trail in Tilden Regional Park in Berkeley, Calif. Photographer: Rachel Bujalski for Bloomberg Businessweek
Krypton $3/liter, 200-liter cylinder

More Hong Kong Lights

Choy Chun Wa, 52, has been working alongside a master neon maker, 78-year-old Wong Kin Wah, for three decades. He mostly focuses on finishing the signs. Choy says he worries constantly that the factory in China that produces the glass tubes will stop making them because of lack of demand. “The future doesn’t look good,” he says. “The biggest threat to our business without a doubt is LEDs.” Wong’s business, in the city’s Mong Kok neighborhood, once included a team of assistants to keep up with demand; in the 1980s he even had a contract to make signs for the local Kentucky Fried Chicken franchises. Today there are fewer than a dozen neon masters like Wong still in business. “I don’t know any young people at all who are doing this work,” Wong says.
Aside from lighting, krypton doesn’t have any commercial uses. It emits a yellow-white color, but the gas isn’t typically used for the color. Krypton is found in airport approach lights and, less frequently, in neon signs. Photographer: Tommy Trenchard for Bloomberg Businessweek
Rubidium $84,400/kg, 99.75%-grade ampoules

Space Commodity

Late last year a team at the U.S. National Institute for Standards and Technology in Boulder, Colo., recorded a clip of Queen and David Bowie’s Under Pressure using excited rubidium and cesium atoms. NIST’s Christopher Holloway says the project grew out of work on atomic sensors, whose potential applications include deep-space communications. In a paper, his team wrote of a desire to inspire others and “help create the future quantum-based workforce.” How, we wondered, might that play out …

  • 2020: Atomic-music stans flood Boulder, aka Quantum Valley
  • 2030: QV builds vast catalog of “rubstep” songs for aliens
  • 2031: Undaunted by lack of market, VCs invest billions
  • 2047: Alien contact: Rubstep broadcasts begin
  • 2069: Callistock held on Jupiter’s 8th moon; profits soar
  • 2099: Teen invents software to distribute rubstep for free
  • 2120: Distressed-asset specialists feast on QV’s bones
Strontium $6.50/kg, 99% strontium metal f.o.b., China market

Name and Shame

Five years ago, Microsoft Corp. founded the Microsoft Threat Intelligence Center (MSTIC, pronounced “mystic”) to track so-called advanced persistent threat groups—sophisticated bands of hackers, often linked to nation-states, that aim to steal secrets and money and to disrupt businesses and elections. MSTIC has christened more than 70 of the groups it tracks with the name of an element. For example, the Russian group responsible for the 2016 hack of the Democratic National Committee, elsewhere called Fancy Bear or APT28, is referred to by MSTIC as Strontium. Why elements? “I didn’t want anything particularly cutesy like ‘kitten,’ ” says John Lambert, who founded the team. And though strontium, an alkali metal, is widely used to make fireworks, the names are chosen randomly. It’s not “like all the noble gases map to Iran or anything,” Lambert says. In 2016, Microsoft sued Strontium in a U.S. court, helping it seize more than 100 website domains linked to the group.

Strontium

  • aka Fancy Bear, APT28
  • Linked to: Russia
  • Known attacks on: Governments, media, and NGOs in Germany, South Africa, the U.K., and the U.S.
  • Recent exploit: Released doping-related International Olympic Committee emails prior to the 2018 Winter Olympics
  • Elemental similarities: Tarnishes in the open

Phosphorus

  • aka APT35, Charming Kitten, Ajax Security Team
  • Linked to: Iran
  • Known attacks on: Political dissidents, media members, NGOs, and governments in Iran, the U.K., and the U.S.
  • Recent exploit: Targeted businesses and government agencies with websites resembling Microsoft and Yahoo ones
  • Elemental similarities: Can cause severe burns

Barium

  • aka Winnti, ShadowHammer, Wicked Panda
  • Linked to: China
  • Known attacks on: Gaming companies, airlines, and hotels in India, Ukraine, and the U.S.
  • Recent exploit: Penetrated a server and inserted a backdoor into an Asus software-update program
  • Elemental similarities: Produces clear view of innards

Thallium

  • aka Kimsuky, Hydra, BabyShark
  • Linked to: North Korea
  • Known attacks on: Governments, NGOs, and media in Japan, the U.K., and the U.S.
  • Recent exploit: Sent emails tricking users into downloading software that could record login credentials
  • Elemental similarities: Toxic and hard to detect
Yttrium $32/kg, metal, Shanghai market

Ore Spot

At least eight elements, all rare earths, can trace their discovery to this mine in Ytterby, Sweden, photographed in 1910. Four are named for the site: yttrium, terbium, erbium, and ytterbium. The others are gadolinium, holmium, scandium, and thulium.
Courtesy Tekniska Museet
Zirconium $13/kg, unwrought import, China market

The Bombmaking Vintner of Colchagua

Carlos Cardoen sold weapons to Saddam Hussein, then became a renowned winemaker in Chile. The U.S. wants him extradited.
The 4th Tactical Fighter Wing ordnance disposal team detonates a cluster bomb during Operation Desert Storm in Iraq. Courtesy NARA

There are certain elements a good winemaker should know. Soil rich in iron, for example, gives merlots and malbecs notes of tobacco, graphite, and mushroom. Calcium and magnesium give pinots the tang of earth, anise, and spices. But there’s another element that Carlos Cardoen, a winemaker in Chile’s bucolic Colchagua Valley, is familiar with for very different reasons.

Cardoen with Hussein. Courtesy U.S. Department of Commerce

A civil engineer with a doctorate in metals science, Cardoen started an explosives company in the 1970s meant to serve the mining industry. With regional tensions rising, Chile’s then dictator, Augusto Pinochet, asked him to start making bombs and land mines. Cardoen’s business soon expanded internationally, and Iraqi leader Saddam Hussein became a fan of his zirconium-laced cluster bombs, designed to blow up and burn a target on impact.

Launched from air or ground, cluster munitions can be bomblets, chemicals, or biological weapons. They can kill indiscriminately across a wide swath of territory, and left undetonated they’re dangerous long after a conflict ends. The Convention on Cluster Munitions, ratified by 120 countries including Chile, prohibits their use, but they were common during Iraq’s wars, responsible for thousands of civilian deaths.

In 1993 the U.S. government charged Cardoen with improperly exporting zirconium, effectively confining him to Chile. He continued building his commercial empire there, spanning mining, agriculture, tourism, renewable energy, and, of course, wine. In so doing, he cultivated relationships with politicians and businesspeople of all stripes. Many Chileans hailed him as a hero and visionary after he helped rebuild communities devastated by a massive earthquake in 2010. His once sleepy hometown of Santa Cruz became an international tourist destination, with a luxury hotel, a personally curated history museum, and the winery, renowned for rich and diverse soil that produces grapes such as carménère, cabernet sauvignon, and tempranillo. The wines are branded with names drawn from Chile’s indigenous peoples: Aymara, Mapuche, Rapa Nui.

That it’s an idyll for oenophiles is fortunate for Cardoen, now 77, who was placed under house arrest in April after an extradition request by the U.S. He declined to comment on the case, but his longtime lawyer, Juan Pablo Hermosilla, calls it “fragile,” saying the U.S. made the extradition request “simply to keep the red alert valid until he dies.” Hermosilla speculates that Interpol, in renewing the notice last year, told the U.S. it needed to do something to pursue the case—“what they should have done 26 years ago.” He adds, “It shows bad faith. They always knew where Carlos was.”

Some Chileans who’ve been avidly following the saga, however, hope it will close an open wound from the Pinochet era. Rodrigo Avilez, a 47-year-old accountant who grew up under the regime, says the case has brought back bad memories. “Justice is delayed,” he says, “but justice arrives eventually.”

Niobium $75.75/kg, 98% China spot

‘I Dream … That One Day, We’ll Also Have a Niobium Valley’

Last year, Brazil produced almost nine-tenths of the world’s niobium, used primarily in steel alloys for airplanes, cars, and electronics. The country’s president, Jair Bolsonaro, who’s long touted the metal’s economic potential, described his “Niobium Valley” dream in a 2016 promotional video. Photographer Júlia Pontés—who took these shots of a niobium mining operation owned by Companhia Brasileira de Metalurgia e Mineração and Chinese partners in Araxá, in the state of Minas Gerais—researches and documents the vast scale of such projects so people can see the effects of mineral exploration and consumption. A Niobium Valley “could be great only if it primarily aimed,” she says, at “benefit for the community.” Extraction industries, she’s found, have returned limited benefits to Araxá’s people. —Jeremy Keehn
Pit at a CBMM niobium mining operation in Araxá, Brazil. Photographer: Júlia Pontés for Bloomberg Businessweek
Minerals gathered for processing. Photographer: Júlia Pontés for Bloomberg Businessweek
Tailings dam. Photographer: Júlia Pontés for Bloomberg Businessweek
Niobium processing plant. Photographer: Júlia Pontés for Bloomberg Businessweek
Molybdenum $24.89/kg, London Metal Exchange cash spot
Technetium Price not available

Moly Cow

A NorthStar machine for producing technetium-99m from molybdenum-99. Courtesy NorthStar

These periodic table neighbors are also kin. Molybdenum-99, an unstable isotope with one neutron more than Mo-98 (the element’s most common naturally occurring form), produces the even more unstable technetium-99m. Tc-99m, as it decays, helps doctors see into the human body, emitting gamma rays that are picked up by specialized cameras in cardiac scans, bone scans, and other imaging procedures.

Traditionally, this unusual supply chain has required irradiating highly enriched uranium—the stuff of nuclear weapons—in reactors overseas, then shipping back the fast-decaying Mo-99. Last year, NorthStar Medical Radioisotopes LLC got permission from the FDA to make it a new way. Discs of stable molybdenum are irradiated in a nuclear reactor in Columbia, Mo., creating Mo-99 that’s then shipped in tungsten-shielded containers to specialized pharmacies. There, NorthStar machines—earlier devices were dubbed “moly cows”—harvest the Tc-99m.

When a hospital orders a scan, the pharmacy prepares a lead-jacketed syringe with Tc-99m and a cocktail of molecules that will bond to the organ of interest. The isotope’s six-hour half-life ensures that it’s gone from the body in days.

Ruthenium $8,819/kg, Johnson Matthey spot
Rhodium $139,509/kg, Johnson Matthey spot
Palladium $47,320/kg, dollar spot

Elements That Go Boom and Bust

Commodities used in small quantities by giant industries have a tendency to undergo spectacular rallies and crashes, especially if they’re produced as byproducts of another material. Their supply doesn’t correspond directly with changes in demand and so doesn’t respond directly to big changes in technology, consumer appetites, or trade relationships. The result is periods of over- or underproduction, with shifting costs to match.

One such set is the platinum group metals, which include ruthenium, rhodium, palladium, and iridium. Dug up as byproducts of platinum in South Africa and nickel in Russia, they’re coveted for their catalytic properties, notably used in cars to turn toxic material into less harmful gases.

Ruthenium

Around 2005, Toshiba, Western Digital, Seagate Technology and other companies started using more ruthenium to increase storage capacity on hard disk drives. The price soared almost 1,500% in two years, but “thrifting”—using less metal to achieve the same results—wiped out the rise by 2009. In 2016 the cloud-storage boom pushed prices higher again, but it’s now hit a plateau as solid-state PC hard drives, which don’t use ruthenium, gain in popularity.

Data: Compiled by Bloomberg

Rhodium

Rhodium was once a favorite of carmakers, who put it in catalytic converters. But around 2003 they found themselves bidding against Sony Corp. and other manufacturers of flatscreen TVs. The price soared 2,000% in five years, only to crash by 90% when car companies started using less and the global financial crisis struck. There was a short-lived recovery in 2009-10, driven by speculators. Lately, they’re betting that auto executives, despite being burned before, will get back in the game.

Data: Compiled by Bloomberg

Palladium

With palladium significantly cheaper than platinum in the 1990s, automakers started shifting to it for gasoline engines. Supply disruptions in Russia around 2000 led to an acute shortage and a price spike, followed by depressed prices as Soviet-era stockpiles were sold off. Automotive demand grew, and, starting in 2012, the world produced less than it consumed for seven straight years. There was a 60% rise in futures in the past year, the largest among 35 key commodities Bloomberg tracks.

Data: Compiled by Bloomberg
Silver $552/kg, London Metal Exchange cash spot

What If You Eat It?

A silver pellet. Photo: SPL/Science Source
  • Who eats silver?
    Colloidal silver—small particles suspended in liquid—was sometimes promoted as a cure-all for hundreds of ailments. But the FDA warned in 1999 that it isn’t safe or effective.
     

  • What does it taste like?
    People describe it as being like “water with a faint metallic taste.”
     

  • What does it do?
    Overexposure causes a condition called argyria, which turns the skin a bluish purple. —Silvia Killingsworth

Cadmium $2.90/kg, metal, U.S. market

Of Crabs and Lichen

A selected list of products that made news in 2019 for containing elevated levels of cadmium, a pervasive environmental contaminant that can, with prolonged exposure, cause bone and kidney damage, as well as some cancers:

  • Plush pencil cases and cartoon-character backpacks sold on Amazon by third-party vendors; Amazon removed them, issued refunds, and agreed to stronger monitoring protocols
Blue crab. Photographer: Prarinya Thonghyad/Alamy
  • Giant mud and blue swimmer crabs harvested from Lake Macquarie, Australia
  • Faux-pearl buttons found on River Island check-pattern dresses and sleeveless blouses; the label recalled the garments
  • Decorative enamels used on a variety of beer, wine, and liquor bottles in the U.K.
  • Diatomaceous earth (a soft sedimentary rock) used for filtration in some wine and beer production
  • Xanthoparmelia scabrosa (aka “sexy pavement lichen”), available on Alibaba as a purported performance enhancer for men
Xanthoparmelia scabrosa. Courtesy D.M.Wright/Lichen Herbarium
Indium $310/kg, free-market price
Tin $16.18/kg, London Metal Exchange cash spot

How Tin Made the World

A bronze ingot from Cyprus. Courtesy Metropolitan Museum of Art

In 1982 a sunken merchant ship from the 14th century B.C. was discovered off the coast of Uluburun, Turkey. Made of cedar and oak, and almost 50 feet long, it was remarkable for the breadth of its cargo. Aboard were goods from at least nine cultures: glass, ebony, elephant ivory, hippopotamus teeth, pine nuts, safflower, pottery, 10 tons of copper—and one ton of tin.

The shipwreck demonstrated that trade routes across continents were already flourishing during the Bronze Age, linking cultures thousands of miles apart. Tin was one of the catalysts. The era draws its name from the fourth millennium B.C. discovery by smiths in Mesopotamia and the Iranian Plateau that alloying copper with a second metal made it stronger, easier to cast, and more resistant to corrosion. The earliest bronzes were made with arsenic, but tin’s superior properties—it didn’t give off toxic fumes when heated, for example—eventually made it the favored alloy.

The strongest bronzes were only about 10% tin, but the element soon became one of the ancient world’s most precious substances. Bronze tools built the first cities, and bronze weapons destroyed them. During the first battle recorded in detail, at Megiddo (in present-day Israel) circa 1500 B.C., Pharaoh Thutmose III crushed a rebellious Canaanite army using bronze weaponry. In the Iliad, Achilles’ armor is forged from copper and tin by Hephaestus, Greek god of smiths. Classical astrologers associated tin with Jupiter, the mightiest of planets.

But tin is rare—30 times less abundant than copper in the Earth’s crust—and unevenly distributed. Where did ancient tin come from? There are no records of major deposits in the northeastern Mediterranean nor in Ancient Egypt. Sumerian texts speak of tin from the east, but there’s no record of its being mined in the Indus Valley Civilization, in present-day Pakistan, either. Even well after the Bronze Age, Herodotus’ Histories spoke of India’s abundant gold, Arabia’s incense and spice, even Ethiopia’s ebony. Yet he could only allude to “Tin Islands, where our tin is brought from,” and about which he knew nothing more.

By the first century A.D., some of the picture was being filled out. The Roman Empire had discovered mines in present-day Cornwall and on the Iberian Peninsula that had likely supplied much of Europe and the Mediterranean. Texts and archaeological digs suggest that tin traveled from Afghanistan west to Mesopotamia and southeast to the Indus Valley. But little more was known until recent decades, when scientific techniques began to trace ancient trade networks with greater certainty.

By analyzing the proportion of different lead isotopes in ore samples taken from sites known to have been exploited in antiquity, researchers have developed “fingerprints” they can match to the metal in some artifacts. The technique, known as lead isotope analysis, has been around since the 1960s, but it’s been challenging to apply to tin because there are very few Bronze Age samples, and cassiterite, the metal’s primary ore, doesn’t generally contain much lead.

Data: Berger et al 2019

Recent advances in lead isotope analysis, however, combined with the study of antimony, indium, silver, and other elements, have let researchers link mid-16th century B.C. tin ingots found in Crete with tin deposits in Afghanistan and Tajikistan, and 13th to 14th century ingots from present-day Israel to Cornwall and the Iberian Peninsula. Researchers publishing in the journal PLOS One this year traced the east-to-west shift in tin supply routes to the decline of the Minoan civilization and the rise of the Mycenaeans, who laid the foundations for Classical Greece.

As for the Uluburun shipwreck, the same researchers lamented that its tin ingots were too corroded for reliable analysis. The best they could say, based on the samples’ low concentration of indium, was that the tin likely didn’t come from Cornwall. With improvements in the science, the picture may fill out more—for now all that’s certain is that traders valued it enough to bring it a long way before it met its watery end.

Antimony $8.60/kg, metal

Explosive Liquid Droplets

Three large fireworks demonstrate the brocade effect and, below that, the glitter effect. Courtesy Thomas H. Handel

Those three words, from a seminal 1978 paper by Nevada biology professor and amateur pyrotechnician Robert Winokur, describe the liquid molten pellets packed with antimony trisulfide that create a glitter effect when ignited. “As the pellets fall through the air, chemistry goes on,” says Winokur, now retired. “Then an array of combustion products are produced by the burning pellet.” There isn’t one magical recipe for the best glitter effect, Winokur says—a typical formula consists of 10% antimony trisulfide, which “increases the delay between the formation of the droplet and the flash reaction.” These days, he adds, a similar effect can be achieved using cheaper, more sulfurous mixes.

Glitter-effect diagrams. Courtesy Robert Winokur
Tellurium $50.50/kg, 99% metal, Rotterdam market

What If You Eat It?

Tellurium. Photographer: Bjorn Wylezich/Alamy
  • Who eats tellurium?
    Very few people; it’s more of an occupational hazard for people working in silver refineries.
     

  • What does it taste like?
    If touched or consumed, the metalloid will instantly metabolize into a compound with a strong garlic smell that can hang around for weeks.
     

  • What does it do?
    Tellurium exposure can cause weight loss or drowsiness, and severe poisoning can slow breathing and stop circulation. —Silvia Killingsworth

Composition

Laser

Lasers are both potent and mundane, high-energy beams that can be used to operate on eyes, precision-cut metal for appliances, and scan bar codes at the corner store. “Light amplification by stimulated emission of radiation” neatly describes how the technology works: Energy is applied to a medium—such as a crystal wafer, liquid solution, or gas—whose particles become stimulated and emit light. Mirrors capture and amplify that light into an intense beam. —E. Tammy Kim

Photographer: Daniel Shea for Bloomberg Businessweek. Product courtesy Trumpf Lasers
Iodine

Salting the Earth

Data: Iodine Global Network

Even as noniodized sea salts are gaining popularity in the U.S., iodization has been a public-health success story globally—ensuring proper body and brain development and preventing issues such as goiters and hypothyroidism. The Iodine Global Network, an alliance of governments, nongovernmental organizations, and industry partners, estimates that a $1 donation provides enough iodized salt to sustain 100 participants in its programs. —Jeremy Keehn

Xenon $25/liter, 200-liter cylinder

More Hong Kong Lights

Brian Kwok, an assistant professor of design at Hong Kong Polytechnic University, has spent the past six years documenting and working to preserve what remains of the city’s neon lights. He says the government should safeguard the more iconic signs, much as it does other parts of the city’s artistic and cultural heritage. He’s helped develop an interactive map of Hong Kong’s last neon signs and gives walking tours and museum talks to raise awareness of the works. “If nobody documents them, we’ll be losing an important part of our visual culture,” he says. “But we have to do it fast—it’s a race against time.”
Xenon emits a bright lavender light. Although rarely used on its own, it’s sometimes combined with other noble gases to create a variety of colored lights. The gas also is used to make strobe lights and flash lighting for cameras. Photographer: Tommy Trenchard for Bloomberg Businessweek
Cesium $78,700/kg, 99.98% metal basis

Chernobyl in the Food Chain

Some of the particles released by the 1986 explosion of Reactor 4 at Chernobyl are no longer radioactive, but one isotope, cesium-137, still is. Winds deposited the material on dry ground nearby in Ukraine, Belarus, and Russia after the accident; a toxic cloud carried more as far away as Ireland. Mixed with rain, it soaked into the ground: “The highest depositions occurred where you had the highest rainfall,” says Nick Beresford, a professor at the Centre for Ecology & Hydrology in Lancaster, U.K. Plants and fungi take up cesium from the soil, and if animals eat them, their meat can be contaminated. Consuming a lot of this meat can cause a moderately higher incidence of cancer, though Jim Smith, a University of Portsmouth professor who’s doing crop experiments near the plant, is quick to note that cesium is “not a massive risk” for the people affected, compared with other environmental hazards.

Norway

Photo: Alamy

Scientists monitor about 90,000 sheep in more than 30 municipalities during the summer season, taking weekly milk samples from ewes to measure radioactivity. If levels are too high, says Runhild Gjelsvik, a scientist at the Norwegian Radiation and Nuclear Safety Authority, flocks are brought down from the hills and given uncontaminated feed until they can be safely slaughtered. Cesium-137 levels in sheep have dropped steeply since 1986, but they rose last year thanks to an abundance of wild mushrooms.

Sweden

Photo: Alamy

Hunters can pay up to 800 kronor ($83) to have boars they shot in riskier areas checked before butchering, according to Per Zakariasson from the Swedish Association for Hunting and Wildlife Management. Last year a wild boar in Uppsala County was found to contain more than twice the legal radioactive cesium limit for boar meat. “The anxiety of the people is a problem. It’s a problem when good, fine meat is thrown away,” Zakariasson says. Authorities have also been monitoring radiation levels in reindeer herded by the indigenous Sami people, who eat a lot of the meat.

Ukraine and Belarus

Photo: Alamy

In the so-called exclusion zones of Ukraine and Belarus, agriculture and forestry remain officially banned, though Smith says recent research shows contamination levels are very diverse. Greenpeace researchers recently found radioactivity levels in milk from some private households and farms in a resettlement area 200 kilometers from the Chernobyl plant were up to six times higher than Ukraine’s legal limit. In 2017, France rejected a shipment of mushrooms from Belarus that showed traces of radioactivity connected to Chernobyl.

Barium $62.55/kg, barium sulfate

Swallow Study

A colored barium-swallow X-ray of a 65-year-old’s abdomen shows a gastric ulcer at lower center. Photo: Zephyr/Science Source

Should you find yourself in need of a live video X-ray of your upper gastrointestinal tract, you have my sympathies. Bracco Diagnostics Inc. manufactures a product called Varibar, a liquid suspension of barium sulfate that comes in an array of flavors and consistencies: thin liquid, nectar, honey, thin honey, and pudding. None can quite mask the reality of ingesting a chalky, room-temperature drink the consistency of a watery milkshake, but taste isn’t the point. Barium on its own can be toxic to humans, but in this form, it’s insoluble and serves as a contrast agent. It shows up white on the X-ray, allowing a doctor to visualize your digestive tract as you swallow. Just try to keep it down.

Lanthanum $5.03/kg, metal, Shanghai market
Cerium $4.89/kg, metal, Shanghai market
Praseodymium $98.40/kg, metal, Shanghai market
Neodymium $56/kg, metal, Shanghai market
Promethium Price not available
Samarium $1.77/kg, 99.9% samarium oxide, China market
Europium $32.56/kg, 99% europium oxide, China market
Gadolinium $26.97/kg, 99.99% gadolinium oxide, China market
Terbium $744/kg, metal, Shanghai market
Dysprosium $326/kg, metal, Shanghai market
Holmium $55.57/kg, 99.5% holmium oxide, China market
Erbium $24.85/kg, 99% erbium oxide, China market

Greenland’s Rare-Earth Minerals Make It Trump’s Treasure Island

The country’s hostile wilderness becomes a new front in the trade war. Read Story
Video: Kiliii Yuyan for Bloomberg Businessweek
Thulium $12,000/kg, 99.95% pure sample on Amazon.com

(Mostly) Useless

A sample of the rare-earth metal thulium. Photo: SLP/Science Source
  • What’s it look like?It’s silvery and shining if preserved in an ampoule of an inert gas such as argon.
  • Why’s it (mostly) useless?Thulium occurs at 0.5 parts per million in the Earth’s crust, and it’s difficult and expensive to extract.
  • What’s it used for?Arc lights use thulium to provide soft green light. Euro banknotes contain traces of thulium and other elements that fluoresce under ultraviolet light, for security. Max Whitby, founder of Red Green & Blue Co. in London, which sells periodic tables that hold element samples, says he once heard of toothpaste containing thulium, but he hasn’t been able to track down the brand.
  • Can I get some?Why yes. A 99.95%-pure gram sample costs $12 on Amazon. A Sunmaster Full Nova 315-watt lamp, which includes not just thulium but dysprosium in its arc element, costs $109.85. A €10 banknote costs €10.
Ytterbium $15.50/kg, 99.99% ytterbium oxide, China market
Lutetium $609/kg, 99.9% lutetium oxide, China market

The Race to Build the World’s Most Precise Clock

Lutetium and ytterbium are vying to become the beating heart of science and the global economy. Read Story
The lutetium-based atomic clock at the National University of Singapore. Photographer: Ore Huiying for Bloomberg Businessweek
Hafnium $775/kg, hafnium, unwrought
Tantalum $245/kg, 99.95% tantalum metal f.o.b., China market
Tungsten $200/MTU (metric ton unit), 88.5% tungsten APT, Rotterdam
Rhenium $2,844/kg, Engelhard spot

The Metals Hunter Scavenging the Globe for Nature’s Rarest Elements

Anthony Lipmann wants what most people can’t find, and he’ll go anywhere to get it. Read Story
Anthony Lipmann, managing director of Lipmann Walton & Co. Photographer: Cristobal Olivares for Bloomberg Businessweek
Osmium $12,860/kg, Engelhard spot
An osmium disc. Photographer: Aaron Wojack for Bloomberg Businessweek

Disco-Dancing German’s Secret Lab Could Disrupt the Diamond Industry

Ingo Wolf is trying to spark demand for one of the rarest elements on the planet. Read Story
Iridium $47,583/kg, Johnson Matthey spot
Platinum $27,521/kg, Johnson Matthey spot

More Elements That Go Boom and Bust

Iridium

The market for iridium—primarily used in sparkplugs and in crucibles for growing crystals to make light-emitting diodes (LEDs)—is much smaller than those for other platinum-group metals; only 7 tons were consumed in 2018, vs. 214 tons of palladium. But iridium still sees jumps—its price rose 150% from 2010 to early 2011, as use in phones and other tech soared. The price slumped starting in 2013 as recycling met demand from phone manufacturers, then climbed again with rising use in the clean production of other chemicals.

Data: Compiled by Bloomberg

Platinum

Platinum’s mid-2000s price spike resulted from a shortage caused by increased use in catalytic converters for gasoline and diesel engines. As it reached record highs in early 2008, the financial crisis struck, carmakers reduced their use, and speculators sold off holdings. Shortages returned and prices went up again for a few years until around 2012, when demand for platinum jewelry declined. In 2015, the Volkswagen AG emissions-testing scandal further hurt the weak market for diesel cars, creating more surpluses and lower prices again.

Data: Compiled by Bloomberg
Gold $48,413/kg, London Metal Exchange cash spot

Some That Glitters Is Recycled

In a twist on the old saying “One man’s trash is another man’s treasure,” the organizing committee of the 2020 Summer Olympics has harnessed the recycling fervor of Japan’s citizenry to source precious metals for the medals that will be awarded at next year’s games. A two-year collection drive that wrapped in March netted almost 79,000 tons of consumer electronics. The labor-intensive process of mining metals from the discarded gadgets has yielded 32 kilograms of gold, 3,500kg of silver, and 2,200kg of copper and zinc—enough to produce more than 5,000 medals.
Unveiled in July, the gold medal designed for the Tokyo Games contains just 6 grams of the precious metal—the minimum required under guidelines issued by the International Olympic Committee. The rest is silver. Courtesy Tokyo 2020
Yellow collection boxes, like this one at a government building in Tokyo, were installed at post offices and on street corners across Japan. Photographer: Carlotta Cardana for Bloomberg Businessweek
More than 6.2 million handsets were donated to the Medal Project. Photographer: Carlotta Cardana for Bloomberg Businessweek
Employees at a facility in Kawasaki owned by Field Environmental Service Inc., one of 50 companies contracted to process the e-waste. A handset’s circuit board contains tiny quantities of precious metals. Photographer: Carlotta Cardana for Bloomberg Businessweek
A dissected camera and phone on display at a collection station. Photographer: Carlotta Cardana for Bloomberg Businessweek
Circuit boards are dunked into chemical solutions that separate gold from other metals. The process is repeated until the desired level of purity—99.9%—is achieved. Photographer: Carlotta Cardana for Bloomberg Businessweek
Gold at different stages of the purifying process. Photographer: Carlotta Cardana for Bloomberg Businessweek
Mercury $48.85/kg, 99.999% metal, China market
Images from advertisements for skin-lightening products. Photo Illustration by 731. Photographs: AP Photo. Getty Images (2)

No One Knows How Many of the World’s Skin-Lightening Creams Are Tainted With Mercury

Tests keep turning up the toxic element, even in products the manufacturers claim are safe. Read Story
Thallium $4,000/kg, U.S. market

(Mostly) Useless

A vial containing a sample of thallium.
  • What’s it look like?Dull and blue-gray, thallium is so quick to tarnish in air that it must be preserved in oil, and so soft it can be cut with a sharp fingernail.
  • Why’s it (mostly) useless?Toxicity. Thallium was a popular rat poison and insecticide ingredient until 1972, when the U.S. government banned its commercial use in rodenticides; other countries followed suit. Thallium is so toxic it can work its way into the body through skin—a property that (spoiler alert!) figures into Agatha Christie’s The Pale Horse.
  • What’s it used for?Combined with sulfur, it enhances conductivity in products like photoreactive sensors. Combined with oxygen, it enhances refractivity in the glass in digital camera lenses and fiber-optic cables. In cardiac stress tests, a small shot of radioactive Tl-201 lights up heart tissue under a gamma camera. (Until alternatives emerge, thallium is perhaps more fairly described as problematically useful.)
  • Can I get some?Probably. Fewer than 8,000 kilograms of the metal are produced each year, but global coal reserves alone contain an estimated 630 million kilograms. Nova Elements sells small nuggets in an argon-filled capsule for €49.90 ($55.40). Alas, $5 jars of thallium-infused Koremlu crème, which in the 1930s promised to remove superfluous body hair with just a daub, are no longer available. A chief symptom of thallium poisoning, not coincidentally, is hair loss.
Composition

MRI Machine

The room-filling magnetic resonance imaging machine, or MRI, is a diagnostic tool used to locate internal injuries and other abnormalities. Giant magnets act upon the hydrogen atoms in the body, spinning the protons in one direction. A radio-frequency current runs through this arrangement, disrupting those protons and, with the help of a computer, measuring the displacement. What results is a 3D image of organs, bones, and tissue. —E. Tammy Kim

Photographer: Daniel Shea for Bloomberg Businessweek. Product courtesy advanced science research center at the graduate center, CUNY.
Lead $2.06/kg, London Metal Exchange cash spot

Lead to Lèad

Lead sample. Photo: Jacana/Science Source

Element 82 has been blamed for the fall of the Roman Empire and for driving Renaissance artists mad. It’s the stuff of bullets and leaded gasoline. And it’s sparked public health crises in Flint, Mich., and Newark, N.J., in recent years, contaminating water supplies and raising blood lead levels in children who were disproportionately from poor and minority communities.

When lead binds with proteins or displaces essential metals in the body, the effects can be catastrophic. “The beauty of lead, for the chemist, is the fact that it can bond in a number of ways,” says Mark Wilson, an assistant professor of chemistry at the University of Toronto. “The danger of lead, for the biologist, is that it can bond in a number of ways.”

But as the chemist might point out, lead isn’t all bad. Lead-based linings protect your organs during X-rays and shield the environment from some hazardous materials. Lead makes your crystal wine glasses strong and sparkly and your car battery rechargeable.

Its usefulness is partly why it’s been pervasive. When the Lead Industries Association went bankrupt in 2002, citing lack of insurance for litigation, no one was left to speak for the positives. With that in mind, Bloomberg Businessweek spoke with Matt Sorrell, creative director of ad agency Wieden + Kennedy, to discuss whether lead’s beneficial uses could in some way redeem it. The interview has been edited for length and clarity.

 

What would you need to know before taking on lead as a client?

Are you trying to educate people? Or is some lead magnate just trying to clear out a warehouse of the stuff?

Let’s start with a brand refresh and let the sales follow from there.

In that case, we would want a forward-looking approach. “Lead Is Life.” “Lead With Lead.” “Lead: Try Not to Think About It Too Much.”

The second one might be tough to understand in print.

Maybe it’s as simple as an accent mark over the “e” or “a” so we get a different pronunciation to make it forward-looking.

Walk us through how you’d pull off “Lead Is Life.”

Lead protects the human body—it protects the genitals of human beings! If you look at it that way, maybe lead creates life.

There is a lot that’s positive about lead. It’s cheap and malleable and tough to corrode. Did you know that the universe is always creating more lead?

I didn’t know that. It’s not going away, so maybe we shouldn’t ignore it.

It also has the highest atomic number of any stable element. That’s what makes it such a great shield against radiation.

Yeah! It’s got a high score, it’s got a high number, but it’s just on the edge of being super dangerous. A maximum-strength Tylenol kind of vibe.

There are plenty of examples of problematic products in the history of advertising—such as cigarettes. What’s the downside of acknowledging the dark side of lead even more overtly?

Bad PR in the ad industry.

But isn’t the ultimate challenge for an agency to persuade people to buy something that’s not good for them?

To sell the unsellable? It feels like a slimy, old-fashioned way to do it, to me. Marlboro Man and [Joe] Camel are weird pieces of pop culture that wouldn’t have existed if people didn’t put their morals aside.

Are you saying the advertising industry has changed?

There’s been change on both ends; public knowledge has also changed. (Pauses.) With information being so readily accessible, people are going to know it’s bad for you. So why hide it? Maybe we embrace it. People do have a kind of doomsday headspace right now. Maybe embracing something that laughs in the face of that could be the way to go? People are into things that are bad for them. “Lead: Expose Yourself.” Or “Lead: Bad to the Bone.” Or “Lead: Hurts So Good.”

Are we talking about award-winning advertising here?

Right now the awards industry is pretty hot on work that takes things to an edgy place and makes people uncomfortable.

Promising. So would you take on lead as a client?

After reviewing the pros and cons? Absolutely not.

Bismuth $10.80/kg, U.S. market

What If You Eat It?

Malaysian bismuth. Photo: Biophoto Assoc/Science Source
  • Who eats bismuth?
    Sufferers of diarrhea, nausea, or upset stomach.
     

  • What does it taste like?
    The most common form, Pepto-Bismol, also known as “pink bismuth,” tastes chalky and a bit medicinal.
     

  • What does it do?
    The active ingredient, bismuth subsalicylate, is used mostly as an antacid, but it also has anti-inflammatory and bactericidal properties that help with diarrhea. And it can turn your tongue and stool black. —Silvia Killingsworth

Polonium $86, 1-inch radioisotope disk

What If You Eat It?

Polonium. Photographer: Richard Treptow/Science Source
Litvinenko Photographer: Alistair Fuller/AP
  • Who eats polonium?
    The Russian spy and defector Alexander Litvinenko, in London in 2006.
     

  • What does it taste like?
    The tea into which it’s been dissolved.
     

  • What does it do?
    Polonium causes fatal radiation exposure. Litvinenko was initially diagnosed with gastroenteritis; within days his blood and bone marrow failed, his hair fell out, and his mucous membranes ulcerated. Eventually, when his organs failed, he fell unconscious and died. —Silvia Killingsworth

Astatine $39.95, uranium + decay

(Mostly) Useless

Uranium is typically found in varying concentrations in an ore called pitchblende, or granite. Courtesy U.S. DOE
  • What’s it look like?No one knows. The best we can do is examine a shard of uranium ore and imagine the hundred or so atoms that lie somewhere in its decaying mass.
  • Why’s it (mostly) useless?If you had a visible quantity, according to the website of the element collector Theodore Gray, “you would be dead, and then it would vanish before your body was cold.” Fortunately, in addition to being wildly radioactive, astatine is the rarest naturally occurring element—fewer than 30 grams are decaying from uranium or thorium in the Earth’s crust at a given time.
  • What’s it used for?Scientists are experimenting with an isotope, At-211, whose low-intensity alpha-particle radiation might kill isolated cancer cells while leaving surrounding healthy tissue unscathed.
  • Can I get some?Not really. You could buy a sample of uranium ore for $39.95 on Amazon and visualize its decay. But for a truly stimulating mental picture, consider tracking down an early 20th century revigator, a water crock made of ceramic treated with uranium or radium ore. People once thought the radioactivity made the water healthier. It didn’t.
Radon $380/kg, thorium oxide + decay

(Mostly) Useless

An NIH radon test kit. Courtesy NIH
  • What’s it look like?Nothing. It’s a colorless, odorless gas.
  • Why’s it (mostly) useless?Its most stable isotope has a half-life of less than four days, decaying first into polonium and eventually into lead.
  • What’s it used for?To locate mineral reserves. Geologists can measure radon content in water and trace it back to deposits of uranium and thorium.
  • Can I get some?If you buy a poorly built house. Radon from decaying uranium or thorium in the ground can spread through cracks in the foundation or plumbing; the Environmental Protection Agency says it’s the leading cause of lung cancer in American nonsmokers. Risk takers can also spend $380 for a kilogram of thorium oxide powder on Alibaba.com; pack some into a glass capsule, and a minute quantity of radon will be inside at all times as the thorium decays. Just hope the glass doesn’t break.
Francium $39.95, uranium + decay

(Mostly) Useless

Interior of the Francium Trapping Facility at Triumf, Canada’s national particle accelerator center, in Vancouver. Photographer: Michael Kossin/FrPNC collaboration
  • What’s it look like?Impossible to say. Given where it appears in the periodic table, scientists suspect francium would look metallic, like other alkalis. But it’s the second-rarest element on Earth, and no one has artificially manufactured more than a few hundred thousand atoms. “If you were ever to look at a piece of pure francium large enough to be visible, it would be the last thing you did,” says Max Whitby of London element-seller Red Green & Blue. “It would explode with the force of a small nuclear bomb.”
  • Why’s it (mostly) useless?The most stable form of francium—produced when actinium, already a fleeting trace element in uranium ore, decays in a particular way—has a half-life of just 20 minutes. It’s also intensely radioactive; Marguerite Perey discovered francium in 1939, and she’d set off nearby radiation counters for years afterward. She died, finally, of bone cancer.
  • What’s it used for?Pretty much just pub trivia. (“A Western European country has not one but two elements named for it. What are they?” Answer: francium and gallium, the latter after Gaul, the old Roman term for France.) “It can’t even be used as a medical isotope,” Whitby says. “How would you transport it anywhere? You’d have only a few minutes to get it there before it decayed.”
  • Can I get some?Apart from the old trick of imagining the appearance and disappearance of francium atoms inside decaying uranium? No.
Radium $100m/kg, in 1921

France Is Still Cleaning Up Marie Curie’s Nuclear Waste

Her lab outside Paris, dubbed Chernobyl on the Seine, is still radioactive nearly a century after her death. Read Story
Curie at her Paris lab in 1925. Photo: Science Source
Actinium Price on request

(Mostly) Useless

A sample of actinium-225 at Oak Ridge National Laboratory’s Radiochemical Engineering Development Center. Courtesy Oak Ridge National Laboratory
  • What’s it look like?In daylight, it’s silvery with a leadlike softness; in the dark, it’s surrounded by a pale blue glow.
  • Why’s it (mostly) useless?It’s frighteningly radioactive, hence the glow.
  • What’s it used for?Xofigo, a Bayer AG drug that treats prostate cancer, has an active ingredient derived from an actinium isotope. Scientists have filed patents to fight cancers with actinium radionuclides, but these aren’t close to full-fledged treatments yet.
  • Can I get some?With difficulty. The most stable isotope, Ac-227, has a half-life of about 21 years, but it’s vanishingly rare—a ton of uranium ore contains just a tenth of a milligram. Most of the world’s supply of Ac-227 is produced for research purposes by the Oak Ridge National Laboratory in Tennessee; glass vials of the stuff are available for purchase by special order. Oak Ridge provides prices on request.
Composition

Catalytic Converter

Four decades ago, this flask-shaped device became standard in cars and trucks. Nondescript on the outside, it transforms the vast majority of poisonous raw engine exhaust into less harmful emissions, without needing additional power. —E. Tammy Kim

Photographer: Daniel Shea for Bloomberg Businessweek. Prop stylist: Anna Surbatovich. Product courtesy Magnaflow
Thorium $72/kg, thorium compounds, India market

Uranium’s Nicer Sister

The Molten Salt Reactor Experiment control room, circa 1965. The experiment achieved its first self-sustaining nuclear reaction on June 1, 1965. Courtesy Oak Ridge National Laboratory

The Problem

Nuclear reactors relying on uranium are prone to major accidents, produce waste that’s hard to dispose of safely, and can make fissile material for weapons.

The Solution?

Thorium is more abundant, less radioactive, produces less waste, and can’t be turned into nukes. The leading proposed technology for thorium power, the molten-salt reactor, also operates under normal atmospheric pressure. So, unlike reactors that use water to moderate nuclear reactions inside containment vessels, there’s no chance of pressure building to the point of explosion if a problem occurs. The technology was demonstrated in U.S. labs in the 1960s, and China and France are working on it again, according to the World Nuclear Association.

The Catch

Designing reactors, a challenge to begin with, is that much harder with an unproven fuel.

Protactinium Price not available

(Mostly) Useless

This sample of protactinium-233 (dark circular area in the photo) was photographed in the light from its own radioactive emission (the lighter area) at the National Reactor Testing Station in Idaho, circa 1969. Courtesy U.S. DOE
  • What’s it look like?In the air it’s bright and silvery for a while before a dark film of oxide gradually creeps over its surface.
  • Why’s it (mostly) useless?Protactinium’s longest-lasting isotope is quite stable, with a half-life of about 32,700 years, but it’s scarce. In uranium ores, it occurs with a frequency of three parts per million, at most. The world’s stock long consisted mainly of 125 grams the U.K. extracted from 60 tons of spent uranium fuel in 1961. Protactinium is now also derived as a byproduct of thorium fission reactors.
  • What’s it used for?Practically nothing. Geologists can compare the concentrations of protactinium and thorium to date marine sediment samples, though the method works only for samples less than 175,000 years old.
  • Can I get some?No. Oak Ridge National Laboratory’s sizable catalog of radioactive elements doesn’t even include protactinium.
Uranium $85.54/kg, average purchase price, U.S. civilian nuclear power reactors

China ❤️ Fission

Nuclear power’s once-bright promise of reliable carbon-free electricity has dimmed the past three decades because of escalating costs, problems with new technologies, and the disasters at Chernobyl and Fukushima. But it’s still pretty bright in China. The International Energy Agency expects its nuclear capacity to grow by 111 gigawatts from 2017 to 2040, and the rest of the world’s to drop by 7GW.

An obvious question, at least for anyone who’s seen HBO’s miniseries Chernobyl, is whether these ambitions risk a repeat of the crises of the past. China hasn’t had any serious nuclear incidents since its first plant began operating in 1991, and the World Nuclear Association praises it for “unprecedented eagerness to achieve the world’s best standards in nuclear safety.” But a report published last year by Mark Hibbs, a senior fellow in the Carnegie Endowment for International Peace’s Nuclear Policy Program, points to several potential challenges. If China builds too many types of reactors—it’s developing three and experimenting with others, including thorium-fueled ones—regulators could find it hard to set standards and conduct inspections. The country also favors parts from a domestic manufacturing industry focused on low costs, a risk when a typical plant needs 3,000 nuclear-grade valves, 250 pumps, 44 miles of piping, 300 miles of electrical wiring, and 90,000 electrical components. “There is a real possibility that this issue may lead to an accident if not rigorously pursued,” Hibbs writes.

Before Fukushima, some estimated that China’s capacity would reach as high as 500 gigawatts, almost five times the current projection. But within a week of a tsunami striking the Japanese nuclear plant, the Chinese government suspended approvals of new nuclear power projects. It later lowered plant-building targets, boosted regulation, and specified that reactor models must feature newer technology to be approved. It again paused approvals in late 2016, though there have been reports the drought will end this year. —With Feifei Shen

Data: World Nuclear Association
Neptunium
Plutonium
Americium
Curium
Berkelium
Californium
Einsteinium
Fermium
Mendelevium
Nobelium
Lawrencium
Rutherfordium
Dubnium
Seaborgium
Bohrium
Hassium
Meitnerium
Darmstadtium
Roentgenium
Copernicium
Nihonium
Flerovium
Moscovium
Livermorium
Tennessine
Oganesson $5.1 million, cost to build Berkeley’s 88-inch cyclotron, 1962
Inside the Lawrence Berkeley National Laboratory. Photographer: Christie Hemm Klok for Bloomberg Businessweek

Making New Elements Doesn’t Pay. Just Ask This Berkeley Scientist

Theorists agree that 119 and 120 are probably within reach, but discovering them will mean wasting time and money. Read Story

The Periodic Table of Totally Awesome Elements

You know vibranium from Black Panther, of course. But that’s not the only element invented for pure entertainment value. We mined the depths of the internet for this superlegit, 100% scientific analysis of the most creative, not-at-all natural wonders. And if you want to argue that some of these are compounds or alloys or whatever, put down the jerktonium and go weave some mithril.

Ad


AdamantiumMarvel Comics

Photo: 20th Century Fox/Everett Collection

Practically indestructible, it’s best known as the steel alloy bonded to Wolverine’s skeleton and claws. According to marvel.com, “Wolverine’s mutant healing factor allowed him to survive the process and induced a molecular change in the metal, transforming it into a wholly new metal, named Adamantium Beta.”

Bo


BologniumThe Simpsons

In “Lisa Gets an ‘A’  ” (1998), bolognium appears on a promotional copy of the periodic table provided to Springfield Elementary by Oscar Mayer. (Mrs. Krabappel: “Now who can tell me the atomic weight of bolognium?” Martin Prince: “Ooh, delicious?” Krabappel: “Correct. I would also accept ‘snacktacular.’ ”)

Bm


BombastiumWalt Disney

Photo: Walt Disney Company/Everett Collection

In a 1957 comic, Uncle Scrooge forks over a chunk of his fortune for a piece “the size of a large turnip,” according to one synopsis. Nobody knows what it does—only that it must remain frozen. “Terrified that his acquisition will melt before he can make a profit,” the review continues, “Scrooge drags Donald Duck and his nephews on a voyage to the South Pole to safeguard his investment.”

Ct


Cobalt Thorium GDr. Strangelove

Photo: Everett Collection

Cobalt and thorium are real elements, but combining them into one is a Hollywood creation, with the “G” possibly distinguishing its radioactive isotope. In the movie, the Russian ambassador says, “If you take, say, 50 H-bombs in the 100-megaton range and jacket them with cobalt thorium G, when they are exploded, they will produce a doomsday shroud.”

Di


DilithiumStar Trek

Photo: Paramount/Everett Collection

Although it exists in reality as two bonded lithium atoms, every Trekkie knows dilithium is a rare crystalline substance that helps power warp-drive propulsion.

En


EnergonTransformers

Photo: Paramount/Everett Collection

According to tfwiki.net, energon is the “preferred fuel of the Transformer race. It takes many forms … but it is most commonly used by Transformers in its liquid state, which is stored in many different mediums, most famously the energon cube.”

Fi


FeminumWonder Woman

Photo: Everett Collection

On the TV show, her Bracelets of Submission were forged of the metal, which made it into the title of two episodes that aired in November 1976: “The Feminum Mystique,” Parts 1 and 2.

Jt


JerktoniumSpongeBob SquarePants

A green substance that turns residents of Bikini Bottom into jerks when ingested. “Infected victims develop big black eyebrows, black bags around their eyes, and a mass of black stubble around their mouths,” according to the Encyclopedia SpongeBobia.

Mi


MithrilThe Lord of the Rings

The lightweight, silvery metal is malleable enough to be made into jewelry or orc-resistant armor.

Un


UnobtaniumAvatar

The metallic, silver-gray mineral, found on the moon Pandora, is a superconductor worth as much as $40 million per kilogram, according to Avatar Wiki. But it predates the movie as a jokey term for a theoretical substance—with perfect properties for some use—that either doesn’t exist or is impossible to mine for political or technological reasons.

Up


UpsidaisiumRocky and His Friends

The antigravity metal is native to a floating mine (bequeathed to Bullwinkle by an uncle), and everyone wants it: the U.S. government, as well as spies Boris and Natasha.

The Elements ● Published August 28, 2019 ● Issue edited by Jeremy Keehn ● Design direction: Chris Nosenzo and Alexander Shoukas in collaboration with Folder Studio ● Development: Folder Studio, James Singleton, Michael Frazer, Andrew LeClair ● Photo: Jane Yeomans, Aeriel Brown, Donna Cohen, Dietmar Liz-Lepiorz ● Video: Diana Suryakusuma, Alexander Shoukas ● Graphics: Dorothy Gambrell, Evan Applegate ● Web production: Emily Engelman, Thomas Houston, Bernadette Walker, Justin McLean, Alexander Shoukas, Andrew LeClair ● Editors: Jim Aley, Ramsey Al-Rikabi, Kristine Aquino, Bret Begun, Max Chafkin, Howard Chua-Eoan, Tina Davis, Daniel Ferrara, Robert Friedman, Eric Gelman, Jillian Goodman, Jeremy Keehn, Dimitra Kessenides, Silvia Killingsworth, Cristina Lindblad, Stephen Merelman, Jeff Muskus, Alaric Nightingale, Sam Potter, Kristin Powers, David Rocks, Lynn Thomasson, Stuart Wallace, Joel Weber ● Copy editors: William Elstrom, Mark Leydorf, Wendy Marcus, Marc Miller, Nicholas Mullan, Anne Newman, David Purcell, Lourdes Valeriano, Brennen Wysong


Periodic table image credits, by atomic number: Photograph by Rocco Rorandelli for Bloomberg Businessweek. Photograph by Adriane Ohanesian for Bloomberg Businessweek. Science Source (16). Courtesy Chris Henshaw. Getty Images (21). Courtesy NASA. Photograph by Evan Ortiz for Bloomberg Businessweek. Photograph by Tommy Trenchard for Bloomberg Businessweek (4). Photograph by Shawn Records for Bloomberg Businessweek. Courtesy Molly M. Peterson/Stone Barns Center for Food and Agriculture. Illustration by Steve Bell. Edward Burtynsky. Courtesy Apple. Courtesy Library of Congress (2). Francesco Bandarin/Unesco. Mauricio Lima/The New York Times/Redux. Alamy (14). Courtesy Nokia Bell Labs. Photograph by Rachel Bujalski for Bloomberg Businessweek. Courtesy Tekniska Museet. Nara. Photograph by Júlia Pontés for Bloomberg Businessweek. Courtesy NorthStar. Courtesy Metropolitan Museum of Art. Courtesy Thomas H. Handel. Photograph by Kiliii Yuyan for Bloomberg Businessweek. Courtesy Department of Energy (4). Photograph by Ore Huiying for Bloomberg Businessweek. Photograph by Cristobal Olivares for Bloomberg Businessweek. Photograph by Aaron Wojack for Bloomberg Businessweek. Photograph by Carlotta Cardana for Bloomberg Businessweek. Photo illustration by 731; source images: Getty Images (2), AP Photo (1), Alamy (1). Courtesy NIH. Michael Kossin/FrPnc Collaboration. Courtesy Oak Ridge National Laboratory (4). Courtesy Lawrence Berkeley National Laboratory (8). Smithsonian Institution Archives. Courtesy National Nuclear Security Administration/Nevada Site Office. A. Zschau/GSI Helmholtzzentrum fur Schwerionenforschung. Smithsonian Institution Archives. AP Photo. Shutterstock. Courtesy JINR. Courtesy LLNL (2) ● Introduction video: Peter Coy; Diana Suryakusuma; Alexander Shoukas; Arthur Woo; Allie Ames